Catalyst-controlled and tunable, chemoselective silver-catalyzed intermolecular nitrene transfer: Experimental and computational studies
NS Dolan, RJ Scamp, T Yang, JF Berry… - Journal of the …, 2016 - ACS Publications
The development of new catalysts for selective nitrene transfer is a continuing area of
interest. In particular, the ability to control the chemoselectivity of intermolecular reactions in
the presence of multiple reactive sites has been a long-standing challenge in the field. In this
paper, we demonstrate examples of silver-catalyzed, nondirected, intermolecular nitrene
transfer reactions that are both chemoselective and flexible for aziridination or C–H
insertion, depending on the choice of ligand. Experimental probes present a puzzling picture …
interest. In particular, the ability to control the chemoselectivity of intermolecular reactions in
the presence of multiple reactive sites has been a long-standing challenge in the field. In this
paper, we demonstrate examples of silver-catalyzed, nondirected, intermolecular nitrene
transfer reactions that are both chemoselective and flexible for aziridination or C–H
insertion, depending on the choice of ligand. Experimental probes present a puzzling picture …
[引用][C] Catalyst-Controlled and Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental and Computational Studies
Y Tzuhsiung - 2016
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