Chemically driven carbon-nanotube-guided thermopower waves

W Choi, S Hong, JT Abrahamson, JH Han, C Song… - Nature materials, 2010 - nature.com
Nature materials, 2010nature.com
Theoretical calculations predict that by coupling an exothermic chemical reaction with a
nanotube or nanowire possessing a high axial thermal conductivity, a self-propagating
reactive wave can be driven along its length. Herein, such waves are realized using a 7-nm
cyclotrimethylene trinitramine annular shell around a multiwalled carbon nanotube and are
amplified by more than 104 times the bulk value, propagating faster than 2 ms− 1, with an
effective thermal conductivity of 1.28±0.2 kW m− 1 K− 1 at 2,860 K. This wave produces a …
Abstract
Theoretical calculations predict that by coupling an exothermic chemical reaction with a nanotube or nanowire possessing a high axial thermal conductivity, a self-propagating reactive wave can be driven along its length. Herein, such waves are realized using a 7-nm cyclotrimethylene trinitramine annular shell around a multiwalled carbon nanotube and are amplified by more than 104 times the bulk value, propagating faster than 2 m s−1, with an effective thermal conductivity of 1.28±0.2 kW m−1 K−1 at 2,860 K. This wave produces a concomitant electrical pulse of disproportionately high specific power, as large as 7 kW kg−1, which we identify as a thermopower wave. Thermally excited carriers flow in the direction of the propagating reaction with a specific power that scales inversely with system size. The reaction also evolves an anisotropic pressure wave of high total impulse per mass (300 N s kg−1). Such waves of high power density may find uses as unique energy sources.
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