Concentrated polymer solutions are different from melts: Role of entanglement molecular weight
Q Huang, O Mednova, HK Rasmussen… - …, 2013 - ACS Publications
Macromolecules, 2013•ACS Publications
We compare viscoelastic properties of several polystyrene solutions and melts with the
same number of entanglements. It is demonstrated that the modulus and time can be shifted
such that the linear viscoelastic properties are identical provided the number of
entanglements are identical. However the nonlinear properties in strong extensional flow
are different with polymer solutions showing markedly stronger extensional hardening than
the corresponding melts. While increased chain extensibility for solutions may provide part …
same number of entanglements. It is demonstrated that the modulus and time can be shifted
such that the linear viscoelastic properties are identical provided the number of
entanglements are identical. However the nonlinear properties in strong extensional flow
are different with polymer solutions showing markedly stronger extensional hardening than
the corresponding melts. While increased chain extensibility for solutions may provide part …
We compare viscoelastic properties of several polystyrene solutions and melts with the same number of entanglements. It is demonstrated that the modulus and time can be shifted such that the linear viscoelastic properties are identical provided the number of entanglements are identical. However the nonlinear properties in strong extensional flow are different with polymer solutions showing markedly stronger extensional hardening than the corresponding melts. While increased chain extensibility for solutions may provide part of the explanation, it is demonstrated that other mechanisms are needed for a full explanation for the differences between solutions and melts.
ACS Publications
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