On the physical interpretation of constant phase elements

MRS Abouzari, F Berkemeier, G Schmitz, D Wilmer - Solid State Ionics, 2009 - Elsevier
… glasses are used to study the deformed shape of impedance semicircles which are usually
described by a parallel circuit of an ohmic resistor and a phenomenological Constant Phase

On the use of a constant phase element (CPE) in electrochemistry

SM Gateman, O Gharbi, HG de Melo, K Ngo… - Current Opinion in …, 2022 - Elsevier
… In practice, the measured capacitance depends on the frequency, and to account for
such behavior, a constant phase element (CPE) is often assumed/used during analysis of …

RC models of a constant phase element

J Valsa, J Vlach - International Journal of Circuit Theory and …, 2013 - Wiley Online Library
The paper describes models of a constantphase element consisting of passive R and C
components. The models offer any input impedance argument (phase) between −90 and 0 over …

Concerning the conversion of the constant phase element parameter Y0 into a capacitance

CH Hsu, F Mansfeld - Corrosion, 2001 - onepetro.org
Constant phase elements (CPE) have become common in fitting procedures of electrochemical
impedance spectra. The impedance of a CPE is given by: Z CPE Y jn ()()??= 0 1?(1) …

The origin of the constant phase element

A Lasia - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
… The constant phase element (CPE) is usually observed at solid electrodes. It is a source of
controversies and misunderstandings. In this Viewpoint, theory, properties, experimental …

The analysis of electrode impedances complicated by the presence of a constant phase element

GJ Brug, ALG van den Eeden… - … chemistry and interfacial …, 1984 - Elsevier
… its phase angle is independent of frequency. This phenomenon of the "constant phase angle…
, gives reason to designate Zc by the name "constant phase element" (CPE), as will be done …

Constant-phase-element behavior caused by resistivity distributions in films: I. Theory

B Hirschorn, ME Orazem, B Tribollet… - Journal of The …, 2010 - iopscience.iop.org
Constant-phase element (CPE) behavior may be attributed to the distribution of physical
properties in films, in the direction normal to the electrode surface. Numerical simulations were …

Note on the parameterization of the constant-phase admittance element

JR Macdonald - Solid State Ionics, 1984 - Elsevier
… expression for the constant-phase element are … of constant phase behavior in the dielectric
response of materials was emphasized by Cole and Cole [I ], who included the constantphase

Constant-phase-element behavior caused by resistivity distributions in films: II. Applications

B Hirschorn, ME Orazem, B Tribollet… - Journal of The …, 2010 - iopscience.iop.org
A normal power-law distribution of local resistivity with a uniform dielectric constant was found
to be consistent with the constant-phase element (CPE). An analytic expression, based on …

Realization of a constant phase difference

S Darlington - The Bell System Technical Journal, 1950 - ieeexplore.ieee.org
constant phase differences under the specific assumption that pairs of constant resistance
phase … the best approximation to a constant phase difference which can be obtained over a …