Electrochemical and Diffusional Investigation of Na2FeIIPO4F Fluorophosphate Sodium Insertion Material Obtained from FeIII Precursor
Sodium iron fluorophosphate (Na2FeIIPO4F) was synthesized by economic solvothermal
combustion technique using FeIII precursors, developing one-step carbon-coated
homogeneous product. Synchrotron diffraction and Mössbauer spectroscopy revealed the
formation of single-phase product assuming an orthorhombic structure (sg Pbcn) with FeII
species. This FeIII precursor derived Na2FeIIPO4F exhibited reversible Na+ (de)
intercalation with discharge capacity of 100 mAh/g at a rate of C/10 involving flat FeIII/FeII …
combustion technique using FeIII precursors, developing one-step carbon-coated
homogeneous product. Synchrotron diffraction and Mössbauer spectroscopy revealed the
formation of single-phase product assuming an orthorhombic structure (sg Pbcn) with FeII
species. This FeIII precursor derived Na2FeIIPO4F exhibited reversible Na+ (de)
intercalation with discharge capacity of 100 mAh/g at a rate of C/10 involving flat FeIII/FeII …
[引用][C] Electrochemical and Diffusional Investigation of Na2FeIIPO4F Fluorophosphate Sodium Insertion Material Obtained from FeIII Precursor
S Lalit, NP Kumar, C Haomin, A Stefan, A Doron… - 2017
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