Electron sponge from naphthalenediimide–viologen conjugates: water-stable, highly electron-deficient polyions with 1 V potential window
Chemical Communications, 2018•pubs.rsc.org
We report a new class of multi-electron acceptors by integrating for the first time multiple π-
cations at the naphthalenediimide-core. These polyions present a remarkably low-lying
LUMO with water stability, seven-redox states in a narrow window of∼ 1 V and excellent
reversibility. Extended conjugation is manifest in mixed valence states with NIR absorption.
X-ray crystallography revealed appealing multiple anion–π interactions.
cations at the naphthalenediimide-core. These polyions present a remarkably low-lying
LUMO with water stability, seven-redox states in a narrow window of∼ 1 V and excellent
reversibility. Extended conjugation is manifest in mixed valence states with NIR absorption.
X-ray crystallography revealed appealing multiple anion–π interactions.
We report a new class of multi-electron acceptors by integrating for the first time multiple π-cations at the naphthalenediimide-core. These polyions present a remarkably low-lying LUMO with water stability, seven-redox states in a narrow window of ∼1 V and excellent reversibility. Extended conjugation is manifest in mixed valence states with NIR absorption. X-ray crystallography revealed appealing multiple anion–π interactions.
The Royal Society of Chemistry