Energetic Trinitro‐and Fluorodinitroethyl Ethers of 1, 2, 4, 5‐Tetrazines
DE Chavez, DA Parrish… - Angewandte Chemie …, 2016 - Wiley Online Library
DE Chavez, DA Parrish, L Mitchell
Angewandte Chemie International Edition, 2016•Wiley Online LibrarySeveral new energetic ethyl ethers of 1, 2, 4, 5‐tetrazine have been synthesized. These
molecules display good thermal stability, good oxygen balance, and high densities. Included
in these studies are a 2, 2, 2‐trinitroethoxy 1, 2, 4, 5‐tetrazine and two fluorodinitroethoxy 1,
2, 4, 5‐tetrazines. One of these compounds was converted into the di‐N‐oxide derivative.
The sensitivity of these materials towards destructive stimuli was determined, and overall the
materials show promising energetic performance properties.
molecules display good thermal stability, good oxygen balance, and high densities. Included
in these studies are a 2, 2, 2‐trinitroethoxy 1, 2, 4, 5‐tetrazine and two fluorodinitroethoxy 1,
2, 4, 5‐tetrazines. One of these compounds was converted into the di‐N‐oxide derivative.
The sensitivity of these materials towards destructive stimuli was determined, and overall the
materials show promising energetic performance properties.
Abstract
Several new energetic ethyl ethers of 1,2,4,5‐tetrazine have been synthesized. These molecules display good thermal stability, good oxygen balance, and high densities. Included in these studies are a 2,2,2‐trinitroethoxy 1,2,4,5‐tetrazine and two fluorodinitroethoxy 1,2,4,5‐tetrazines. One of these compounds was converted into the di‐N‐oxide derivative. The sensitivity of these materials towards destructive stimuli was determined, and overall the materials show promising energetic performance properties.
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