Enhancement of hydrogen sorption properties of MgH2 with a MgF2 catalyst

JS Youn, DT Phan, CM Park, KJ Jeon - International Journal of Hydrogen …, 2017 - Elsevier
International Journal of Hydrogen Energy, 2017Elsevier
Abstract Effect of a MgF 2 catalyst, prepared by ball-milling, on the hydrogen desorption
ability of commercial MgH 2 was investigated. When MgH 2 was catalyzed with a MgF 2
composite, it exhibited good cyclability and sharp faceting, with a small grain size (around
10 nm), which differs from those of pure MgH 2. The addition of the MgF 2 catalyst suggests
that the F anion could significantly contribute to the cyclability of Mg particles and aid in the
inhibition of MgH 2 grain growth.
Abstract
Effect of a MgF2 catalyst, prepared by ball-milling, on the hydrogen desorption ability of commercial MgH2 was investigated. When MgH2 was catalyzed with a MgF2 composite, it exhibited good cyclability and sharp faceting, with a small grain size (around 10 nm), which differs from those of pure MgH2. The addition of the MgF2 catalyst suggests that the F anion could significantly contribute to the cyclability of Mg particles and aid in the inhibition of MgH2 grain growth.
Elsevier
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