Following dynamic nuclear wave packets in N, and CO with few-cycle infrared pulses
S De, M Magrakvelidze, IA Bocharova, D Ray… - Physical Review A …, 2011 - APS
Physical Review A—Atomic, Molecular, and Optical Physics, 2011•APS
We study the evolution of nuclear wave packets launched in molecular nitrogen, oxygen,
and carbon monoxide by intense 8-fs infrared pulses. We use velocity map imaging to
measure the momentum of the ion fragments when these wave packets are interrogated by
a second such pulse after a variable time delay. Both quasibound and dissociative wave
packets are observed. For the former, measurements of bound-state oscillations are used to
identify the participating states and, in some cases, extract properties of the relevant …
and carbon monoxide by intense 8-fs infrared pulses. We use velocity map imaging to
measure the momentum of the ion fragments when these wave packets are interrogated by
a second such pulse after a variable time delay. Both quasibound and dissociative wave
packets are observed. For the former, measurements of bound-state oscillations are used to
identify the participating states and, in some cases, extract properties of the relevant …
We study the evolution of nuclear wave packets launched in molecular nitrogen, oxygen, and carbon monoxide by intense 8-fs infrared pulses. We use velocity map imaging to measure the momentum of the ion fragments when these wave packets are interrogated by a second such pulse after a variable time delay. Both quasibound and dissociative wave packets are observed. For the former, measurements of bound-state oscillations are used to identify the participating states and, in some cases, extract properties of the relevant potential-energy surfaces. Vibrational structure is resolved in both energy and oscillation frequencies for the cations of oxygen and carbon monoxide, displaying the same quantum wave-packet motion in both energy and time domains. In addition, vibrational structure is seen in the dication of carbon monoxide in a situation where the energy resolution by itself is inadequate to resolve the structure.
American Physical Society
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