Formal nickelate (− I) complexes supported by group 13 ions
MV Vollmer, J Xie, RC Cammarota… - Angewandte Chemie …, 2018 - Wiley Online Library
Formal nickelate (− I) complexes bearing Group 13 metalloligands (M= Al and Ga) were
isolated. These 17 e− complexes were synthesized by one‐electron reduction of the
corresponding Ni0→ MIII precursors, and were investigated by single‐crystal X‐ray
diffraction, EPR spectroscopy, and quantum chemical calculations. Collectively, the
experimental and computational data support: 1) the strengthening of the Ni− M bond upon
one‐electron reduction, and 2) the delocalization of the unpaired spin across the Ni and M …
isolated. These 17 e− complexes were synthesized by one‐electron reduction of the
corresponding Ni0→ MIII precursors, and were investigated by single‐crystal X‐ray
diffraction, EPR spectroscopy, and quantum chemical calculations. Collectively, the
experimental and computational data support: 1) the strengthening of the Ni− M bond upon
one‐electron reduction, and 2) the delocalization of the unpaired spin across the Ni and M …
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