Hexaaryltetragermabuta‐1, 3‐diene: A Molecule with Conjugated Ge− Ge Double Bonds
H Schäfer, W Saak… - Angewandte Chemie …, 2000 - Wiley Online Library
H Schäfer, W Saak, M Weidenbruch
Angewandte Chemie International Edition, 2000•Wiley Online LibraryThe longest wavelength absorption of the dark blue solution of the tetragermabutadiene 1
(Tip= 2, 4, 6‐iPr3C6H2) in n‐hexane at 560 nm indicates a pronounced conjugation of the
two Ge− Ge double bonds. In the crystal, 1 adopts the s‐cis conformation with a dihedral
angle for the Ge4 framework of 22.5°.
(Tip= 2, 4, 6‐iPr3C6H2) in n‐hexane at 560 nm indicates a pronounced conjugation of the
two Ge− Ge double bonds. In the crystal, 1 adopts the s‐cis conformation with a dihedral
angle for the Ge4 framework of 22.5°.
The longest wavelength absorption of the dark blue solution of the tetragermabutadiene 1 (Tip=2,4,6‐iPr3C6H2) in n‐hexane at 560 nm indicates a pronounced conjugation of the two Ge−Ge double bonds. In the crystal, 1 adopts the s‐cis conformation with a dihedral angle for the Ge4 framework of 22.5°.
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