The production of H₂-rich gaseous mixtures from steam reforming of crude glycerol was investigated on ternary Ni–La–Ti catalysts. Ni–La–Ti mixed oxides containing 15 wt% of Ni and a La/Ti atomic ratio of 1 were prepared by a coprecipitation method and characterized by a variety of physical and spectroscopic techniques. Samples were calcined in air at 700 °C or 850 °C for 2 h. Ni–La–Ti samples calcined at 700 °C (NiLaTi700) showed a well-defined NiO phase and an amorphous La–Ti mixed oxide, while those calcined at 850 °C (NiLaTi850), exhibited two well defined phases of NiO and LaTiO₃ perovskite, respectively. NiO was completely reduced to metallic Ni on both solids under pure H₂ at 650 °C and the resulting Ni⁰ phase remained as a separate phase under the steam reforming conditions. Standard catalytic tests for the steam reforming of glycerol were performed at 500 °C or 650 °C by feeding the fixed-bed tubular reactor with a crude glycerol:water solution containing 30 wt% glycerol. The best results were achieved on NiLaTi700 at 650 °C, obtaining H₂ yields and H₂/CO₂ molar ratios close to the theoretical values predicted by the steam reforming reaction stoichiometry. A slight activity decay was observed on NiLaTi700 with the progress of the reaction, probably reflecting the formation of small amounts of coke.