Inside Front Cover: From Coordination Polymer Macrocrystals to Nanometric Individual Chains (Adv. Mater. 14/2005)

D Olea, SS Alexandre, P Amo‐Ochoa… - Advanced …, 2005 - Wiley Online Library
Advanced Materials, 2005Wiley Online Library
Isolated single chains of the coordination polymer [Cd (6‐MCP) 2] n (6‐MCP= 6‐
mercaptopurinate) can be prepared by ultrasonic dispersion, ultracentrifugation, and
deposition on a treated mica surface, and the mechanical and electrical properties are
reported on p. 1761 by Zamora and co‐workers. The observed insulating behavior of the
chains can be confirmed using density functional theory calculations. The inside cover
shows atomic force microscopy images of the resultant chains at increasing magnification.
Abstract
Isolated single chains of the coordination polymer [Cd(6‐MCP)2]n (6‐MCP = 6‐mercaptopurinate) can be prepared by ultrasonic dispersion, ultracentrifugation, and deposition on a treated mica surface, and the mechanical and electrical properties are reported on p. 1761 by Zamora and co‐workers. The observed insulating behavior of the chains can be confirmed using density functional theory calculations. The inside cover shows atomic force microscopy images of the resultant chains at increasing magnification.
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