… We speculate that the mechanism of H/D exchange in this system is similar to the one …
Because heterogeneous Rd and Pt catalysts have been shown to catalyze H/D exchange, 1 we …

… Development of an achiral Ir catalyst Our investigation of iridium complex-catalyzed H/D
exchange reactions with different substrate classes revealed that ThrePHOX 18 b is one of the …

… by the present catalytic system. In addition, the H/D exchange of methylidene groups …
Unfortunately, however, the present catalytic system cannot be applied to the H/D exchange …

… advantage delivered by these novel iridium catalyst systems. To the best of … iridium
phosphine/carbene species for H/D exchange, and with an improved understanding of the catalytic …

… Screening a number of compounds has shown that the iridium catalyst has the ability to
catalyze H/D exchange in an array of compounds. These include unsaturated carboxylic acids, …

… The catalytic H/D exchange reaction between benzene and … H/D exchange in other arenes.
Branched alkyl substituents in alkyl aromatics showed an affinity toward deuterium exchange …

… Cationic iridium complexes are particularly suited for the activation of CH bonds, 50 for
which reason iridium-mediated H/D-exchange reactions make up by far the greatest number of …

… A variety of aromatic substrates were screened for H/D exchange using 5 mol % of the
trihydride iridium catalyst 4 in acetone-d 6 . Table 2 lists these substrates and their corresponding …

… is attributed to the “umpolung” of a deuterium atom of D 2 O through a rapid H + /D +
exchange with the iridium catalyst. To the best of our knowledge, this is the first example of the …

… Herein, we report an efficient iridium(I)-catalyzed C–H activation method for the hydrogen
isotope exchange of sp 3 C–H bonds. A wide range of substrates have been labeled, including …