Janus Electrolyte with Modified Li+ Solvation for High‐Performance Solid‐State Lithium Batteries
Advanced Functional Materials, 2022•Wiley Online Library
Solid‐state lithium‐metal batteries attract great attention due to their high energy density and
superior safety. However, the sluggish Li+ kinetics of solid electrolyte and poor interface
compatibility between electrolyte and lithium anode lead to unsatisfied performance at room
temperature, which severely limit their practical application. Herein, a Janus quasi‐solid
electrolyte (JSE) design is reported, which modifies the Li+ solvation environment in
succinonitrile (SN) plastic crystal electrolyte and creates 1D Li+ transportation channels …
superior safety. However, the sluggish Li+ kinetics of solid electrolyte and poor interface
compatibility between electrolyte and lithium anode lead to unsatisfied performance at room
temperature, which severely limit their practical application. Herein, a Janus quasi‐solid
electrolyte (JSE) design is reported, which modifies the Li+ solvation environment in
succinonitrile (SN) plastic crystal electrolyte and creates 1D Li+ transportation channels …
Abstract
Solid‐state lithium‐metal batteries attract great attention due to their high energy density and superior safety. However, the sluggish Li+ kinetics of solid electrolyte and poor interface compatibility between electrolyte and lithium anode lead to unsatisfied performance at room temperature, which severely limit their practical application. Herein, a Janus quasi‐solid electrolyte (JSE) design is reported, which modifies the Li+ solvation environment in succinonitrile (SN) plastic crystal electrolyte and creates 1D Li+ transportation channels. Density functional theory calculations and Raman results reveal that Li1.3Al0.3Ti1.7(PO4)3 changes the Li+ solvation environment from SN units to aggregated ion pairs, which accelerates the diffusion rate of Li+. As a result, JSE presents excellent ionic conductivity (0.73 mS cm−1) and high lithium transference number (0.72). With this efficient JSE, Li symmetric cells deliver excellent cycle stability over 600 h with a low over potential of 60 mV. LiFePO4|JSE|Li solid‐state battery delivers an impressive performance with a specific discharge capacity of 152 mAh g−1 after 100 cycles at room temperature under 0.5 C. Moreover, the corresponding pouch cell also shows outstanding performance (140 mAh g−1 under 0.5 C) and withstands abuse tests such as bending and cutting, demonstrating its superior safety for future utilization.
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