Manganese–cobalt oxido cubanes relevant to manganese-doped water oxidation catalysts
Incorporation of Mn into an established water oxidation catalyst based on a Co (III) 4O4
cubane was achieved by a simple and efficient assembly of permanganate, cobalt (II)
acetate, and pyridine to form the cubane oxo cluster MnCo3O4 (OAc) 5py3 (OAc= acetate,
py= pyridine)(1-OAc) in good yield. This allows characterization of electronic and chemical
properties for a manganese center in a cobalt oxide environment, and provides a molecular
model for Mn-doped cobalt oxides. The electronic properties of the cubane are readily tuned …
cubane was achieved by a simple and efficient assembly of permanganate, cobalt (II)
acetate, and pyridine to form the cubane oxo cluster MnCo3O4 (OAc) 5py3 (OAc= acetate,
py= pyridine)(1-OAc) in good yield. This allows characterization of electronic and chemical
properties for a manganese center in a cobalt oxide environment, and provides a molecular
model for Mn-doped cobalt oxides. The electronic properties of the cubane are readily tuned …
[引用][C] Manganese–Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts
SD LM, BR David, TT Don - 2017
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