Microwave-assisted peroxidative oxidation of toluene and 1-phenylethanol with monomeric keto and polymeric enol aroylhydrazone Cu (II) complexes
Cu (II) complexes in two different tautomeric forms (keto and enol) derived from the
aroylhydrazone Schiff base 2-hydroxy (2-hydroxybenzylidene) benzohydrazide (H 2 L) have
been synthesized and characterized by elemental analysis, IR spectroscopy, ESI-MS and
single crystal X-ray crystallography. While the compound with the enol form of the ligand
exists as the 1D polymer [Cu (1κNOO', 2κO', 3κO”-L)] n (1), that with the keto form of the
ligand occurs as the monomer [Cu (κNOO'-HL) Cl (CH 3 OH)](2). Both complexes act as …
aroylhydrazone Schiff base 2-hydroxy (2-hydroxybenzylidene) benzohydrazide (H 2 L) have
been synthesized and characterized by elemental analysis, IR spectroscopy, ESI-MS and
single crystal X-ray crystallography. While the compound with the enol form of the ligand
exists as the 1D polymer [Cu (1κNOO', 2κO', 3κO”-L)] n (1), that with the keto form of the
ligand occurs as the monomer [Cu (κNOO'-HL) Cl (CH 3 OH)](2). Both complexes act as …
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