Mixed diboration of alkenes in a metal-free context
Chemical Communications, 2015•pubs.rsc.org
… In order to have more insight into the mechanism of the metal-free mixed diboration
reaction, we conducted DFT calculations 14 with the aim to understand the intrinsic control
of the regioselectivity. Bo and co-workers have computationally characterised the
mechanism of the organocatalytic … In summary, we have found that mixed diboration
reactions with the Bpin–Bdan reagent, can be carried out in a metal-free context, with high
control of regioselectivity, locating the Bdan unit in the internal position. Ten new diborated …
reaction, we conducted DFT calculations 14 with the aim to understand the intrinsic control
of the regioselectivity. Bo and co-workers have computationally characterised the
mechanism of the organocatalytic … In summary, we have found that mixed diboration
reactions with the Bpin–Bdan reagent, can be carried out in a metal-free context, with high
control of regioselectivity, locating the Bdan unit in the internal position. Ten new diborated …
Experimental and theoretical rationalization on regioselective mixed diboration of alkenes, with the unsymmetrical diboron reagent Bpin–Bdan, providing the protecting Bdan moiety in the internal position.
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