Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction
The first nickel-catalyzed intramolecular hydroacylation/Suzuki cross coupling cascade of o-
allylbenzaldehydes with a broad range of phenylboronic acid neopentyl glycol esters has
been developed. This strategy shows high regioselectivity and step economy in the
construction of two C–C bonds via aldehyde C–H bond activation, affording valuable
indanones with high efficiency.
allylbenzaldehydes with a broad range of phenylboronic acid neopentyl glycol esters has
been developed. This strategy shows high regioselectivity and step economy in the
construction of two C–C bonds via aldehyde C–H bond activation, affording valuable
indanones with high efficiency.
The first nickel-catalyzed intramolecular hydroacylation/Suzuki cross coupling cascade of o-allylbenzaldehydes with a broad range of phenylboronic acid neopentyl glycol esters has been developed. This strategy shows high regioselectivity and step economy in the construction of two C–C bonds via aldehyde C–H bond activation, affording valuable indanones with high efficiency.
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