On the luminescence of bis (triphenylphosphine) phenanthroline copper (I)

G Blasse, DR McMillin - Chemical Physics Letters, 1980 - Elsevier
… Recently some copper(i) complexes have been shown to luminescence in solution [ 1.21. In
view of the fact that the ligands involved have low-lying, unoccupied ?r* levels the emission was
ascribed tentatively to metal-to-l&and … Srnce some of the complexes involved show efficrent
lummescence at room temperature in the solid state, we extended the previous work to
sohd-state luminescence … [7] this IS ascribed to an increase of electronic interactions between
adJacent copper Ions m the excited state with lowering temperature_ Decay tunes reported m …
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