On the role of heterogeneous chemistry in ozone depletion and recovery

C Wilka, K Shah, K Stone, S Solomon… - Geophysical …, 2018 - Wiley Online Library
Geophysical Research Letters, 2018Wiley Online Library
We demonstrate that identification of stratospheric ozone changes attributable to ozone
depleting substances and actions taken under the Montreal Protocol requires evaluation of
confounding influences from volcanic eruptions. Using a state‐of‐the‐art chemistry‐climate
model, we show that increased stratospheric aerosol loading from volcanic eruptions after
2004 impeded the rate of ozone recovery post‐2000. In contrast, eruptions increased ozone
loss rates over the depletion era from 1980 to 1998. We also present calculations without …
Abstract
We demonstrate that identification of stratospheric ozone changes attributable to ozone depleting substances and actions taken under the Montreal Protocol requires evaluation of confounding influences from volcanic eruptions. Using a state‐of‐the‐art chemistry‐climate model, we show that increased stratospheric aerosol loading from volcanic eruptions after 2004 impeded the rate of ozone recovery post‐2000. In contrast, eruptions increased ozone loss rates over the depletion era from 1980 to 1998. We also present calculations without any aerosol chemistry to isolate contributions from gas‐phase chemistry alone. This study reinforces the need for accurate information regarding stratospheric aerosol loading when modeling ozone changes, particularly for the challenging task of accurately identifying the early signs of ozone healing distinct from other sources of variability.
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