PXPd-catalyzed borylation of aniline derivatives
SL Wheaton, SM Humanayun Kabir, H Zhang… - … European Journal of …, 2010 - Springer
Central European Journal of Chemistry, 2010•Springer
Addition of pinacolborane (HBO 2 C 2 Me 4) to 2-iodoaniline can be catalyzed using a
number of palladium complexes, including [(t-Bu) 2 PCl] 2 PdCl 2 (PXPd), to give the
corresponding boronate ester 2-H 2 NC 6 H 4 (BO 2 C 2 Me 4) in excellent yields. The PXPd
system could also be used in the catalyzed borylation of substituted anilines to give the
corresponding aminoboronate esters in moderate to high yields.
number of palladium complexes, including [(t-Bu) 2 PCl] 2 PdCl 2 (PXPd), to give the
corresponding boronate ester 2-H 2 NC 6 H 4 (BO 2 C 2 Me 4) in excellent yields. The PXPd
system could also be used in the catalyzed borylation of substituted anilines to give the
corresponding aminoboronate esters in moderate to high yields.
Abstract
Addition of pinacolborane (HBO2C2Me4) to 2-iodoaniline can be catalyzed using a number of palladium complexes, including [(t-Bu)2PCl]2PdCl2 (PXPd), to give the corresponding boronate ester 2-H2NC6H4(BO2C2Me4) in excellent yields. The PXPd system could also be used in the catalyzed borylation of substituted anilines to give the corresponding aminoboronate esters in moderate to high yields.
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