Plasmon hybridization in nanoparticles near metallic surfaces

P Nordlander, E Prodan - Nano Letters, 2004 - ACS Publications
Nano Letters, 2004ACS Publications
We apply the recently developed plasmon hybridization method to a solid nanosphere
interacting with a metallic surface. We show that the plasmon energies of the nanoparticle
exhibit strong shifts with nanoparticle− surface separation. Depending on the energy of the
surface plasmon, nanoparticle plasmons can either red shift or blue shift with decreasing
nanoparticle− surface separation. The shifts can be explained as resulting from image-like
interactions with the metal surface and, more importantly, through hybridization between the …
We apply the recently developed plasmon hybridization method to a solid nanosphere interacting with a metallic surface. We show that the plasmon energies of the nanoparticle exhibit strong shifts with nanoparticle−surface separation. Depending on the energy of the surface plasmon, nanoparticle plasmons can either red shift or blue shift with decreasing nanoparticle−surface separation. The shifts can be explained as resulting from image-like interactions with the metal surface and, more importantly, through hybridization between the nanoparticle plasmons and the delocalized surface plasmons of the substrate.
ACS Publications
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