Real-time observation of the formation of excited radical ions in bimolecular photoinduced charge separation: Absence of the Marcus inverted region explained
M Koch, A Rosspeintner, K Adamczyk… - Journal of the …, 2013 - ACS Publications
Unambiguous evidence for the formation of excited ions upon ultrafast bimolecular
photoinduced charge separation is found using a combination of femtosecond time-resolved
fluorescence up-conversion, infrared and visible transient absorption spectroscopy. The
reaction pathways are tracked by monitoring the vibrational energy redistribution in the
product after charge separation and subsequent charge recombination. For moderately
exergonic reactions, both donor and acceptor are found to be vibrationally hot, pointing to an …
photoinduced charge separation is found using a combination of femtosecond time-resolved
fluorescence up-conversion, infrared and visible transient absorption spectroscopy. The
reaction pathways are tracked by monitoring the vibrational energy redistribution in the
product after charge separation and subsequent charge recombination. For moderately
exergonic reactions, both donor and acceptor are found to be vibrationally hot, pointing to an …
[引用][C] Real-Time Observation of the Formation of Excited Radical Ions in Bimolecular Photoinduced Charge Separation: Absence of the Marcus Inverted Region …
K Marius, R Arnulf, A Katrin, L Bernhard, D Jens, NE TJ… - 2013
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