Human emotion reflected in facial expression is generated by coordinated operation of muscular movement of facial tissue which associates with the emotional state of the human subject. Facial expression is one of the most significant non-articulated forms of social communication and it is highly adopted by scientific community for the purpose of automated emotion analysis. In the present scope, a triangular structure is induced with three points, viz., circumcenter, incenter, and centroid are considered as the geometric primitive for extraction of relevant features. Information extracted from such features is utilized for the purpose of discrimination of one expression from another using MultiLayer Perceptron (MLP) classifier in images containing facial expressions available in various benchmark databases. Results obtained by applying this method found to be extremely encouraging.