Oscillatory kinetics in heterogeneous catalysis
R Imbihl, G Ertl - Chemical Reviews, 1995 - ACS Publications
… oscillatory changes in the state of the catalyst itself during rate oscillations on a supported Pt
… A very simple model demonstrating the influence of spatial inhomogeneities of the catalyst …
… A very simple model demonstrating the influence of spatial inhomogeneities of the catalyst …
A new model for oscillatory behaviour in closed systems: the autocatalator
P Gray, SK Scott - Berichte der Bunsengesellschaft für …, 1986 - Wiley Online Library
… to introduce simple consistent models for oscillating chemical reactions. Oscillatory behaviour …
The cubic autocatalytic step followed by catalyst decay (called the autocatalator in the cstr …
The cubic autocatalytic step followed by catalyst decay (called the autocatalator in the cstr …
Oscillatory catalytic reactions at single-crystal surfaces
G Ertl - Advances in catalysis, 1990 - Elsevier
… The success of this simple model is considered as additional confirmation of the conclusion,
that the CO-induced structural transformation of the surface causing an alteration of the …
that the CO-induced structural transformation of the surface causing an alteration of the …
A study on energy and time description of the catalytic act with the selective energy transfer and impulse oscillation models
R Larsson, MA Borowiak - Journal of Molecular Catalysis A: Chemical, 2001 - Elsevier
… of catalysts, based on two complementary models with vibrational modes as the primary
molecular parameters for description of catalysis … Let us consider the simplest catalytic reaction …
molecular parameters for description of catalysis … Let us consider the simplest catalytic reaction …
Mathematical modeling of kinetic oscillations in the catalytic CO oxidation on Pd (110): The subsurface oxygen model
MR Bassett, R Imbihl - The Journal of chemical physics, 1990 - pubs.aip.org
… model, however, in order to keep the model as simple as possible. Calculations which included
this effect showed only minor differences compared to the simpler model. … of oscillation …
this effect showed only minor differences compared to the simpler model. … of oscillation …
Chemical oscillations by substrate inhibition: a parametrically universal oscillator type in homogeneous catalysis by metal complex formation
FF Seelig - Zeitschrift für Naturforschung A, 1976 - degruyter.com
… and some simple and widely adjustable models that can lead to a successful design of
new oscillators and which should therefore not contain such strange assumptions, like …
new oscillators and which should therefore not contain such strange assumptions, like …
Oscillations, period doublings, and chaos in CO oxidation and catalytic mufflers
M Marek, M Schejbal, P Kočí, V Nevoral… - … Journal of Nonlinear …, 2006 - pubs.aip.org
… catalytic oxidation and relate it to the function of catalytic … catalytic oxidation of CO is the most
often studied oscillatory … numerical modeling is then used to show that, in addition to simple …
often studied oscillatory … numerical modeling is then used to show that, in addition to simple …
Oscillatory oxidation of CO over a Pt catalyst
… be demonstrated below, one can obtain an excellent qualitative understanding of the
reaction kinetics and the likely origin of the oscillations with a very simple model for the reaction. …
reaction kinetics and the likely origin of the oscillations with a very simple model for the reaction. …
Unstable and oscillatory behaviour in heterogeneous catalysis
E Wicke, P Kummann, W Keil… - Berichte der …, 1980 - Wiley Online Library
… the catalyst surface we finally need a regeneration process that provides for a recovery of the
reaction rate in the oscillation … of some simple examples of chemical reactors. The moving …
reaction rate in the oscillation … of some simple examples of chemical reactors. The moving …
Oscillatory oxidation of CO over Pt, Pd and Ir catalysts: Theory
… A simple physical model is presented to explain the oscillatory oxidation of CO over Pt. Pd
and Ir catalysts. Oscillations are believed to occur between two … The kinetics of the oscillatory …
and Ir catalysts. Oscillations are believed to occur between two … The kinetics of the oscillatory …
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