Solid‐state structure of free base guanidine achieved at last
T Yamada, X Liu, U Englert, H Yamane… - … A European Journal, 2009 - Wiley Online Library
T Yamada, X Liu, U Englert, H Yamane, R Dronskowski
Chemistry–A European Journal, 2009•Wiley Online LibraryAbstract “Crystal structure of the free base guanidine determined 148 years after the first
synthesis”: A prototype structure unveiled—despite its provocative simplicity, the crystal
structure of guanidine has not been previously described. 148 years after the first synthesis
of guanidine, we now find two Y‐shaped symmetry‐independent molecules in the unit cell
that are interconnected by a hydrogen‐bonding network, which results in a fascinating
layered structure (see picture).
synthesis”: A prototype structure unveiled—despite its provocative simplicity, the crystal
structure of guanidine has not been previously described. 148 years after the first synthesis
of guanidine, we now find two Y‐shaped symmetry‐independent molecules in the unit cell
that are interconnected by a hydrogen‐bonding network, which results in a fascinating
layered structure (see picture).
Abstract
“Crystal structure of the free base guanidine determined 148 years after the first synthesis”: A prototype structure unveiled—despite its provocative simplicity, the crystal structure of guanidine has not been previously described. 148 years after the first synthesis of guanidine, we now find two Y‐shaped symmetry‐independent molecules in the unit cell that are interconnected by a hydrogen‐bonding network, which results in a fascinating layered structure (see picture).
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