We study the 24-hour spectrum usage pattern in Singapore in the frequency bands ranging from 80 MHz to 5850 MHz. The objectives are to find how the scarce radio spectrum allocated to different services is utilized in Singapore and identify the bands that could be accessed for future opportunistic use due to their low or no active utilization. The results from the spectrum measurements taken over 12 weekday periods reveal that a significant amount of spectrum in Singapore has very low occupancy all the time. The occupancy is quantified as the amount of spectrum detected above a certain received power threshold. The outcome of this study suggests that Singapore has a great potential for employing emerging spectrum sharing technology such as the cognitive radio technology to accommodate enormous demands for future wireless services. However, this study of spectrum survey is preliminary in its nature and future long term studies need to be performed to determine any potential secondary usage on those channels that have low or no active utilization.