Spin dynamics in electrochemically charged CdSe quantum dots

NP Stern, M Poggio, MH Bartl, EL Hu, GD Stucky… - Physical Review B …, 2005 - APS
Physical Review B—Condensed Matter and Materials Physics, 2005APS
We use time-resolved Faraday rotation to measure coherent spin dynamics in colloidal
CdSe quantum dots charged in an electrochemical cell at room temperature. Filling of the 1
S e electron level is demonstrated by the bleaching of the 1 S e− 1 S 3∕ 2 absorption peak.
One of the two Landé g factors observed in uncharged quantum dots disappears upon filling
of the 1 S e electron state. The transverse spin-coherence time, which is over 1 ns and is
limited by inhomogeneous dephasing, also appears to increase with charging voltage. The …
We use time-resolved Faraday rotation to measure coherent spin dynamics in colloidal CdSe quantum dots charged in an electrochemical cell at room temperature. Filling of the electron level is demonstrated by the bleaching of the absorption peak. One of the two Landé factors observed in uncharged quantum dots disappears upon filling of the electron state. The transverse spin-coherence time, which is over and is limited by inhomogeneous dephasing, also appears to increase with charging voltage. The amplitude of the spin precession signal peaks near the half-filling potential. Its evolution at charging potentials without any observable bleaching of the transition suggests that the spin dynamics are influenced by low-energy surface states.
American Physical Society
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