Switching of charge transport pathways via delocalization changes in single-molecule metallacycles junctions
To explore the charge transport through metalla-aromatics building blocks, three
metallacycles complexes were synthesized, and their single-molecule conductances were
characterized by using mechanically controllable break junction technique. It is found that
the conductance of the metallacycles junction with phosphonium group is more than 1 order
of magnitude higher than that without phosphonium group. X-ray diffraction and UV–vis
absorption spectroscopy suggested that the attached phosphonium group makes …
metallacycles complexes were synthesized, and their single-molecule conductances were
characterized by using mechanically controllable break junction technique. It is found that
the conductance of the metallacycles junction with phosphonium group is more than 1 order
of magnitude higher than that without phosphonium group. X-ray diffraction and UV–vis
absorption spectroscopy suggested that the attached phosphonium group makes …
[引用][C] Switching of Charge Transport Pathways via Delocalization Changes in Single-Molecule Metallacycles Junctions
L Ruihao, L Zhengyu, C Yuanting, J Feng, T Chun… - 2017
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