Synthesis, Structure and Magnetic Properties of Mn2Tb2 Tetranuclear Complex with p‐tert‐Butylthiacalix[4]arene
SM Aldoshin, IS Antipin, MV Kniazeva… - Israel Journal of …, 2020 - Wiley Online Library
Abstract A new tert‐buthylthiacalix [4] arene‐based tetranuclear 3d‐4f metal complex with
the Mn2Tb2 core has been synthesized and its molecular and crystal structures have been
studied by X‐ray diffraction. The complex geometry is similar to that of the earlier
synthesized tert‐buthylthiacalix [4] arene‐based M2Ln2 complexes with M= Mn (II), Co (II),
and Ln= Gd, Pr, Eu, but unlike those systems, it exhibits intricated cooperative low‐
temperature magnetic properties arising from the presence of intercluster interactions. At T< …
the Mn2Tb2 core has been synthesized and its molecular and crystal structures have been
studied by X‐ray diffraction. The complex geometry is similar to that of the earlier
synthesized tert‐buthylthiacalix [4] arene‐based M2Ln2 complexes with M= Mn (II), Co (II),
and Ln= Gd, Pr, Eu, but unlike those systems, it exhibits intricated cooperative low‐
temperature magnetic properties arising from the presence of intercluster interactions. At T< …
Synthesis, Structure and Magnetic Properties of Mn2Tb2 Tetranuclear Complex with p-tert-Butylthiacalix[4]arene
AV Palii, SE Solovieva, RB Morgunov, IS Antipin… - dspace.kpfu.ru
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim A new tert-buthylthiacalix [4] arene-
based tetranuclear 3d-4f metal complex with the Mn2Tb2 core has been synthesized and its
molecular and crystal structures have been studied by X-ray diffraction. The complex
geometry is similar to that of the earlier synthesized tert-buthylthiacalix [4] arene-based
M2Ln2 complexes with M= Mn (II), Co (II), and Ln= Gd, Pr, Eu, but unlike those systems, it
exhibits intricated cooperative low-temperature magnetic properties arising from the …
based tetranuclear 3d-4f metal complex with the Mn2Tb2 core has been synthesized and its
molecular and crystal structures have been studied by X-ray diffraction. The complex
geometry is similar to that of the earlier synthesized tert-buthylthiacalix [4] arene-based
M2Ln2 complexes with M= Mn (II), Co (II), and Ln= Gd, Pr, Eu, but unlike those systems, it
exhibits intricated cooperative low-temperature magnetic properties arising from the …