The Ar–HF intermolecular potential: Overtone spectroscopy and ab initio calculations
The vibrational dependence of the intermolecular potential of Ar–HF is investigated through
the spectra of levels correlating with HF (v= 3). We have previously reported measurements
of the (vbKn)=(3000),(3100), and (3110) levels of Ar–HF using intracavity laser‐induced
fluorescence in a slit supersonic jet [J. Chem. Phys. 98, 2497 (1993)]. These levels are found
to be well reproduced (within 0.1 cm− 1) by the Ar–HF H6 (4, 3, 2) potential [J. Chem. Phys.
96, 6752 (1992)]. The second overtone experiments are extended to include the (3002) state …
the spectra of levels correlating with HF (v= 3). We have previously reported measurements
of the (vbKn)=(3000),(3100), and (3110) levels of Ar–HF using intracavity laser‐induced
fluorescence in a slit supersonic jet [J. Chem. Phys. 98, 2497 (1993)]. These levels are found
to be well reproduced (within 0.1 cm− 1) by the Ar–HF H6 (4, 3, 2) potential [J. Chem. Phys.
96, 6752 (1992)]. The second overtone experiments are extended to include the (3002) state …
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