… of the Mo3S44+ ion by employing the … Mo3S44+(aq) ion on an absolute scale, an accurately
weighedamount of the [Mo3S4(HNTA)3]2" compound was completely hydrolyzed, the ion …

… a lower oxidation state of Mo3S44+. If M2+ coordinates with Mo3S44+ prior to reduction, the
… µ-sulfido ligands of a transient reduced form of Mo3S44+. The incomplete cube has three …

… With use of the NaBH4 method and the aqua ion of Mo202S22+ (G) as the Mov2 reactant, …
be converted to Mo3S44+. However, formation of Mo3(S)OS24+ rather than Mo3S44+ is so …

… We have recently reported on the preparation and properties of Mo3S44+ aqua ion (I).1 A
… We describe here the reaction of the aqua ion I with metallic iron as follows: Mo3S44+ + Fe - …

… of the Mo3S44+(aq) ion by … Mo3S44+(aq) ion there was a second, paler green ion (denoted
II) that adhered more firmly to the resin. From the eluate containing this second green ion we …

… -type Mo3S44+ aquaion (1) with metallic iron gives the cubane-type Mo3FeS44+ aqua ion,…
(NH3)9(H20)]C14 derived from the aqua ion and ammonia water.1 We will describe here the …

… On reduction of the aqua ion at a constant potential of -0.15 V (… temperature) gives the
MoIV3 ion Mo3S44+. The behavior … It is now accepted that the green aqua ion used as starting …

… The reactivityof the aqua ion with Hg is very low in contrast to the case of the Mo3S44+ aqua
ion.9b The W3S44+ aqua ion in 2 Mhc1 reacts rapidly with reductants(eg, NaBH4, Sn, and …

… The fact that the 5+ Mo3FeS4 cube is highly reactive with a second mole of oxidant and then
breaks down to give Mo3S44+ is consistent with the removal of MM bonding. An alternative …

… -type aqua cluster ions with Mo3MS4 cores as shown in Scheme I. The reaction of the aqua
ion A with divalent metal ions in … Without the use of the aqua ion A, mixed-metal clusters with …