Increasing demand for energy worldwide, driven largely by the developing world, coupled with the tremendous hidden costs associated with traditional energy sources necessitates an unprecedented fraction of the future global energy mix come from sustainable, renewable sources. The potential solar energy resource dwarfs that of all other renewable sources combined, yet only two photovoltaic technologies are known to have the potential to be scaled up to make dramatic impact on the overall energy mix: silicon and organic photovoltaics. In this paper, we present the long-term sustainability advantages of organics when compared to silicon and other photovoltaic technologies in terms of energy payback time and global warming potential while also discussing the outlook for transitional applications of organic solar cells.