Thermodynamic− Kinetic Correlations in Supercooled Liquids: A Critical Survey of Experimental Data and Predictions of the Random First-Order Transition Theory of …
JD Stevenson, PG Wolynes - The Journal of Physical Chemistry B, 2005 - ACS Publications
The Journal of Physical Chemistry B, 2005•ACS Publications
Thermodynamics and kinetics are thought to be linked in glass transitions. The quantitative
predictions of α-relaxation activation barriers provided by the theory of glasses based on
random first-order transitions are compared with the experimental results for 44 substances.
The agreement found between the predicted activation energies near T g and experiment is
excellent. These predictions depend on the configurational heat capacity change on
vitrification and the entropy of melting the crystal which are experimental inputs.
predictions of α-relaxation activation barriers provided by the theory of glasses based on
random first-order transitions are compared with the experimental results for 44 substances.
The agreement found between the predicted activation energies near T g and experiment is
excellent. These predictions depend on the configurational heat capacity change on
vitrification and the entropy of melting the crystal which are experimental inputs.
Thermodynamics and kinetics are thought to be linked in glass transitions. The quantitative predictions of α-relaxation activation barriers provided by the theory of glasses based on random first-order transitions are compared with the experimental results for 44 substances. The agreement found between the predicted activation energies near Tg and experiment is excellent. These predictions depend on the configurational heat capacity change on vitrification and the entropy of melting the crystal which are experimental inputs.
ACS Publications以上显示的是最相近的搜索结果。 查看全部搜索结果