Many ruinous pollutants are omnipresent in the environment and among them; pesticides are xenobiotic and pose to be a bio-recalcitrance. Their detrimental ecological and environmental impacts attract attention of environmental excerpts and the surge of stringent regulations have endows the need of a technically feasible treatment. This critical review emphasizes about the occurrence, abundance and fate of structurally distinct pesticides in different environment. The practiced remedial strategies and in particular, the advanced oxidation processes (AOPs) those utilize the photo-catalytic properties of nano-composites for the degradation of pollutants are critically discussed. Photo-catalytic degradation utilizes many composite materials at nano-scale level, wherein synthesis of nano-composites with appropriate precursors and other adjoining functional moieties are of prime importance. Therefore, suitable starter materials along with the reaction conditions are prerequisite for effectively tailoring the nano-composites. The aforementioned aspects and their customized applications are critically discussed. The associated challenges, opportunities and process economics of degradation using photo-catalytic AOP techniques are highlighted and in addition, the review tries to explain how best the photo-degradation can be a stand-alone tool with a societal importance. Conclusively, the future prospects for undertaking new researches in photo-catalytic breakdown of pollutants that can be judiciously sustainable.