Dynamic covalent chemistry (DCC) opens up a fascinating route for the construction of well‐
organized supramolecular architectures, starting from organic molecular cages to crystalline
macromolecular covalent organic frameworks (COFs). Herein, for the first time, we have
manifested a facile room‐temperature DCC‐directed transformation of discrete organic
imine cage‐to‐COF film at the liquid–liquid interface. The unfolding of the cage leading to
the generation of imine intermediates, followed by their interface‐assisted preorganization …

Abstract Covalent Organic Frameworks, Dynamic Covalent Chemistry, Interfacial
Transformation, Molecular Cage, Molecular Sieving The transformation of imine cages into a
covalent organic framework film through dynamic covalent chemistry at the liquid-liquid
interface is reported by Abhijit Patra et al. in their Research Article (e202219083). Keywords:
Covalent Organic Frameworks; Dynamic Covalent Chemistry; Interfacial Transformation;
Molecular Cage; Molecular Sieving EN Covalent Organic Frameworks Dynamic Covalent …