Tuning the interactions in the spin-ice materials by silicon substitution

T Stöter, M Antlauf, L Opherden, T Gottschall… - Physical Review B, 2019 - APS
T Stöter, M Antlauf, L Opherden, T Gottschall, J Hornung, J Gronemann, T Herrmannsdörfer…
Physical Review B, 2019APS
We report that the lattice constant of Dy 2 Ge 2− x Si x O 7 (x= 0, 0.02, 0.08, 0.125) can be
systematically reduced by substituting the nonmagnetic germanium ion in the cubic
pyrochlore oxide with silicon. A multianvil high-pressure synthesis was performed up to 16
GPa and 1100∘ C to obtain polycrystalline samples in a solid-state reaction. Measurements
of magnetization, ac susceptibility, and heat capacity reveal the typical signatures of a spin-
ice phase. From the temperature shift of the peaks, observed in the temperature-dependent …
We report that the lattice constant of (, 0.02, 0.08, 0.125) can be systematically reduced by substituting the nonmagnetic germanium ion in the cubic pyrochlore oxide with silicon. A multianvil high-pressure synthesis was performed up to 16 GPa and to obtain polycrystalline samples in a solid-state reaction. Measurements of magnetization, ac susceptibility, and heat capacity reveal the typical signatures of a spin-ice phase. From the temperature shift of the peaks, observed in the temperature-dependent heat capacity, we deduce an increase in the strength of the exchange interaction. In conclusion, the reduced lattice constant leads to a changed ratio of the competing exchange and dipolar interaction. This puts the new spin-ice compounds closer towards the phase boundary of a short-range spin-ice arrangement and antiferromagnetic long-range order consistent with an observed reduction in the energy scale of monopole excitations.
American Physical Society
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