Tuning the packing density of host molecular self-assemblies at the solid–liquid interface using guest molecule
… In this work, we first utilize THB as the guest molecule to tune the packing motifs of 1,3,5-tris(10-ethoxycarbonyldecyloxy)
benzene (TECDB, Scheme 1) self-assembly and form the honeycomb structure. Our study
illustrates that by sensible choice of guest … So we conclude that the concentration
dependence is directly related to the difference of stability in the porous and linear
polymorphs and their respective molecular densities. These results provide not only insight
into the thermodynamics of the formation of surface-confined nanopatterns at the solid–liquid …
benzene (TECDB, Scheme 1) self-assembly and form the honeycomb structure. Our study
illustrates that by sensible choice of guest … So we conclude that the concentration
dependence is directly related to the difference of stability in the porous and linear
polymorphs and their respective molecular densities. These results provide not only insight
into the thermodynamics of the formation of surface-confined nanopatterns at the solid–liquid …
The use of THB molecules as a guest template tunes the formation of a two-dimensional honeycomb network in preference to alternative close packed structures of TECDB self-assembled on HOPG surface at the solid–liquid interface.
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