Two new lanthanide members of francisite family Cu3Ln (SeO3) 2O2Cl (Ln= Eu, Lu)
KV Zakharov, EA Zvereva, ES Kuznetsova… - Journal of Alloys and …, 2016 - Elsevier
KV Zakharov, EA Zvereva, ES Kuznetsova, PS Berdonosov, VA Dolgikh, MM Markina…
Journal of Alloys and Compounds, 2016•ElsevierTwo new lanthanide compounds, Cu 3 Ln (SeO 3) 2 O 2 Cl, Ln= Eu and Lu, with mineral
francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld
refinement of the structure results in orthorhombic unit cell, space group Pmmn. The
arrangement of magnetically active Cu 2+ ions in francisite structure corresponds to buckled
kagomé type lattice. Both compounds were characterized in measurements of ac-magnetic
susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the …
francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld
refinement of the structure results in orthorhombic unit cell, space group Pmmn. The
arrangement of magnetically active Cu 2+ ions in francisite structure corresponds to buckled
kagomé type lattice. Both compounds were characterized in measurements of ac-magnetic
susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the …
Abstract
Two new lanthanide compounds, Cu3Ln(SeO3)2O2Cl, Ln = Eu and Lu, with mineral francisite structure were synthesized under vacuum in sealed quartz tubes. The Rietveld refinement of the structure results in orthorhombic unit cell, space group Pmmn. The arrangement of magnetically active Cu2+ ions in francisite structure corresponds to buckled kagomé type lattice. Both compounds were characterized in measurements of ac-magnetic susceptibility, dc-magnetization, X-band electron spin resonance and specific heat in the range 2–320 K under magnetic field up to 9 T. The ferromagnetic interactions dominate in both compounds at elevated temperatures. The Eu (Lu) francisite manifests antiferromagnetic order at TN = 36 (38) K and undergoes the field-induced metamagnetic transition into canted ferrimagnetic state at BC = 2.6 (3.0) T. The magnetization loops of both compounds evidence hysteretic behavior above BC.
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