Unveiling nanometer scale extinction and scattering phenomena through combined electron energy loss spectroscopy and cathodoluminescence measurements

A Losquin, LF Zagonel, V Myroshnychenko… - Nano …, 2015 - ACS Publications
Plasmon modes of the exact same individual gold nanoprisms are investigated through
combined nanometer-resolved electron energy-loss spectroscopy (EELS) and
cathodoluminescence (CL) measurements. We show that CL only probes the radiative
modes, in contrast to EELS, which additionally reveals dark modes. The combination of both
techniques on the same particles thus provides complementary information and also
demonstrates that although the radiative modes give rise to very similar spatial distributions …
Plasmon modes of the exact same individual gold nanoprisms are investigated through combined nanometer-resolved electron energy-loss spectroscopy (EELS) and cathodoluminescence (CL) measurements. We show that CL only probes the radiative modes, in contrast to EELS, which additionally reveals dark modes. The combination of both techniques on the same particles thus provides complementary information and also demonstrates that although the radiative modes give rise to very similar spatial distributions when probed by EELS or CL, their resonant energies appear to be different. We trace this phenomenon back to plasmon dissipation, which affects in different ways the plasmon signatures probed by these techniques. Our experiments are in agreement with electromagnetic numerical simulations and can be further interpreted within the framework of a quasistatic analytical model. We therefore demonstrate that CL and EELS are closely related to optical scattering and extinction, respectively, with the addition of nanometer spatial resolution.
ACS Publications
以上显示的是最相近的搜索结果。 查看全部搜索结果