d-Glucosamine as an efficient ligand for the copper-catalyzed selective synthesis of anilines from aryl halides and NaN 3

KG Thakur, KS Srinivas, K Chiranjeevi, G Sekar - Green Chemistry, 2011 - pubs.rsc.org
KG Thakur, KS Srinivas, K Chiranjeevi, G Sekar
Green Chemistry, 2011pubs.rsc.org
D-Glucosamine is introduced for the first time as a green ligand with copper in a coupling
reaction to synthesize anilines. The reaction proceeds in a domino fashion by the in
situreduction of aryl azides formed from aryl halides and NaN3. The high water solubility of
the ligand enables easy catalyst removal.
D-Glucosamine is introduced for the first time as a green ligand with copper in a coupling reaction to synthesize anilines. The reaction proceeds in a domino fashion by the in situreduction of aryl azides formed from aryl halides and NaN3. The high water solubility of the ligand enables easy catalyst removal.
The Royal Society of Chemistry
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