Equilibrium relationships for non-equilibrium chemical dependencies
It is shown that equilibrium constants determine the time-dependent behavior of particular
ratios of concentrations for any system of reversible first-order reactions. Indeed, some …
ratios of concentrations for any system of reversible first-order reactions. Indeed, some …
Extended detailed balance for systems with irreversible reactions
AN Gorban, GS Yablonsky - Chemical Engineering Science, 2011 - Elsevier
The principle of detailed balance states that in equilibrium each elementary process is
equilibrated by its reverse process. For many real physico-chemical complex systems (eg …
equilibrated by its reverse process. For many real physico-chemical complex systems (eg …
[HTML][HTML] Thermodynamic driving forces and chemical reaction fluxes; reflections on the steady state
M Pekař - Molecules, 2020 - mdpi.com
Molar balances of continuous and batch reacting systems with a simple reaction are
analyzed from the point of view of finding relationships between the thermodynamic driving …
analyzed from the point of view of finding relationships between the thermodynamic driving …
Independence of chemical reactions
R Aris, RHS Mah - Industrial & Engineering Chemistry …, 1963 - ACS Publications
A systematic treatment is given for evaluating the stoichiometry of a chemical reaction
system on the basis of limited experimental observations. It is shown that the number of …
system on the basis of limited experimental observations. It is shown that the number of …
Kinetics of coupled reversible reactions
GN Vriens - Industrial & Engineering Chemistry, 1954 - ACS Publications
MANY chemical processes ofindustrial importance behave kinetically like a system of
coupled—ie, consecutive, or parallel—first-order, reversible reactions. This may be so even …
coupled—ie, consecutive, or parallel—first-order, reversible reactions. This may be so even …
A generalization of Wegscheider's condition. Implications for properties of steady states and for quasi-steady-state approximation
S Schuster, R Schuster - Journal of Mathematical Chemistry, 1989 - Springer
A generalization of Wegschcider's condition concerning equilibrium constants in chemically
reacting systems is formulated, which is then proved to be a necessary and sufficient …
reacting systems is formulated, which is then proved to be a necessary and sufficient …
Thermodynamics of chemical coupling
CJ Pings, EB Nebeker - Industrial & Engineering Chemistry …, 1965 - ACS Publications
The applicability of irreversible thermodynamics to coupled chemical reactions is discussed.
Coupling is distinguished from the common phenomenon of interference, and a sufficient …
Coupling is distinguished from the common phenomenon of interference, and a sufficient …
Analytical solution for networks of irreversible first-order reactions
GR Eykholt - Water Research, 1999 - Elsevier
A new analytical solution technique for networks of irreversible chemical reactions in batch
reactors with first-order kinetics is presented. The solution technique involves the iterative …
reactors with first-order kinetics is presented. The solution technique involves the iterative …
Nonuniqueness of equilibria in closed reacting systems
HG Othmer - Chemical Engineering Science, 1976 - Elsevier
While the equilibrium point in an ideal closed reacting system is unique and globally stable,
it is shown herein that nonideal systems can have multiple equilibria and that more than one …
it is shown herein that nonideal systems can have multiple equilibria and that more than one …
Molecular thermodynamics of chemical reactions
CA Eckert - Industrial & Engineering Chemistry, 1967 - ACS Publications
Many recent studies in chemical reaction kinetics have been directedtoward the physical
aspects of the reactor problem—optimization, reactor dynamics, transport phenomena …
aspects of the reactor problem—optimization, reactor dynamics, transport phenomena …