Carbon–carbon (C–C) coupling is critically important in organic synthesis. Direct C–C
coupling to replace two C–H bonds is preferred over coupling of two prefunctionalized C …

Copper salts find widespread use in Pd-catalyzed oxidation reactions, and they are typically
used as oxidants or redox-active cocatalysts. Here, we probe the origin of a dramatic …

In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed
oxidative coupling via C–H functionalization of aromatic, benzylic and allylic C–H bonds …

Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …

We discovered a cooperative gold/silver catalysis mechanism in the oxidative cross-
coupling reaction between 1, 2, 4, 5-tetrafluorobenzene and N-TIPS-indole, using DFT …

With an ever-increasing emphasis on green synthesis of chemicals, there has been growing
interest in deoxygenative conversion of alcohols as widely available organic feedstocks for …

The Ni‐catalyzed C (sp2)− H/C (sp3)− H coupling of benzamides with toluene derivatives
was recently successfully achieved with mild oxidant iC3F7I. Herein, we employ density …

Copper-promoted inert C (sp3)–H functionalization has gradually been developed as a
nascent tool to establish categories of bonds, including C (sp3)–C, C (sp3)–N, C (sp3)–O/S …

Copper-catalyzed selective coupling of C (sp3)–H bonds with C (sp2)–H bonds has been
developed. An aniline module was used as a directing group to generate an aminyl radical …

This review explores the pivotal role of sulfur in advancing sustainable carbon‐carbon (C−
C) coupling reactions. The unique electronic properties of sulfur, as a soft Lewis base with …