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The enantioselective, intramolecular arylcyanation of unactivated olefins via C− CN bond
activation has been accomplished using a Ni (0) catalyst and BPh3 co-catalyst. High …

A catalyst system derived from nickel and cocatalytic AlMe2Cl effects the intramolecular
arylcyanation of alkenes. The reaction takes place in an exclusive exo-dig manner to give a …

Herein, a highly regio-, enantio-, and diastereoselective nickel-catalyzed desymmetric
hydrocyanation of biaryl dienes for the simultaneous construction of axial and central …

A highly effective asymmetric version of α‐cyanation of β‐keto esters and amides was
developed with a Lewis‐acid catalyst. Thus, by using 10 mol% of a tridentate bisoxazoline …

A diastereoselective Pd-catalyzed arylcyanation/heteroarylcyanation of chiral N-
allylcarboxamides using Zn (CN) 2 as the cyanide source is reported. Nitrile-containing …

An enantioselective electrophilic α-cyanation of 1-indanone-derived β-keto esters and β-
keto amides using a hypervalent iodine as the cyanide-transfer reagent was realized. A …

The first example of catalytic asymmetric electrophilic cyanation of 3-substituted oxindoles
has been achieved using readily accessible 4-acetylphenyl cyanate as the cyano source …

A nickel-catalyzed enantioselective hydrocyanation of N-aryl 5-norbornene-endocis-2, 3-
dicarboximides was reported. This desymmetrization process allows for a quick construction …

Enantioselective hydrocyanation of N-benzyloxycarbonyl aldimines catalyzed by a Ru [(S)-
phgly] 2 [(S)-binap]/C6H5OLi system or a bimetallic complex [Li {Ru [(S)-phgly] 2 [(S) …