Blockiness and sequence polydispersity effects on the phase behavior and interfacial properties of gradient copolymers
We consider the influence of sequence polydispersity upon the phase behavior and
interfacial characteristics of gradient copolymers. By adapting the algorithmic procedure …
interfacial characteristics of gradient copolymers. By adapting the algorithmic procedure …
Gradient copolymers–Preparation, properties and practice
Gradient copolymers are members of a unique class of copolymer in which the monomer
composition changes gradually from one end of the polymer chain to the other. In general …
composition changes gradually from one end of the polymer chain to the other. In general …
Interfacial activity of gradient copolymers
KR Shull - Macromolecules, 2002 - ACS Publications
Numerical self-consistent field (SCF) theory is used to study the equilibrium segregation of
A/B gradient copolymers to the interface between immiscible A and B homopolymers. A …
A/B gradient copolymers to the interface between immiscible A and B homopolymers. A …
Effect of Gradient Sequencing on Copolymer Order–Disorder Transitions: Phase Behavior of Styrene/n-Butyl Acrylate Block and Gradient Copolymers
MM Mok, CJ Ellison, JM Torkelson - Macromolecules, 2011 - ACS Publications
We investigate the effect of gradient sequence distribution in copolymers on order–disorder
transitions, using rheometry and small-angle X-ray scattering to compare the phase …
transitions, using rheometry and small-angle X-ray scattering to compare the phase …
Phase behavior of gradient copolymers
R Jiang, Q Jin, B Li, D Ding, RA Wickham… - Macromolecules, 2008 - ACS Publications
A multiblock model is developed for the study of the phase behavior of gradient copolymers.
The model is able to describe gradient copolymer chains with arbitrary composition profiles …
The model is able to describe gradient copolymer chains with arbitrary composition profiles …
Phase behavior of ternary homopolymer/gradient copolymer blends
The phase behavior of ternary homopolymer/gradient copolymer blends is studied
theoretically using a multiblock model of gradient copolymers. Critical lines and Lifshitz …
theoretically using a multiblock model of gradient copolymers. Critical lines and Lifshitz …
Gradient copolymers
U Beginn - Colloid and polymer science, 2008 - Springer
Gradient copolymers represent a relative new class of copolymers containing at least one
section of the macromolecule where the chemical composition continuously changes along …
section of the macromolecule where the chemical composition continuously changes along …
Phase segregation in gradient copolymer melts
MD Lefebvre, M Olvera de La Cruz, KR Shull - Macromolecules, 2004 - ACS Publications
Local segregation in melts of copolymers with composition gradients along their backbones
is analyzed. The transition to a lamellar periodic structure as the effective degree of …
is analyzed. The transition to a lamellar periodic structure as the effective degree of …
Gradients in homopolymers, blends, and copolymers
CF Jasso-Gastinel - Modification of Polymer Properties, 2017 - Elsevier
In homopolymers with additives, blends, and copolymers, synergism can be accomplished
in the structure/property/cost relationships if a proper gradient in components compositions …
in the structure/property/cost relationships if a proper gradient in components compositions …
Phase behavior of gradient copolymer solutions: a Monte Carlo simulation study
We use computer simulations to study the phase separation behavior of amphiphilic linear
gradient copolymer solution under poor solvent conditions. Using the bond fluctuation model …
gradient copolymer solution under poor solvent conditions. Using the bond fluctuation model …
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