Experimental evidence for kinetic effects on B/Ca in synthetic calcite: implications for potential B (OH) 4− and B (OH) 3 incorporation

J Uchikawa, DE Penman, JC Zachos… - … et Cosmochimica Acta, 2015 - Elsevier
The boron to calcium ratio (B/Ca) in biogenic CaCO 3 is being increasingly utilized as a
proxy for past ocean carbonate chemistry. However, B/Ca of cultured and core-top …

Influence of solution chemistry on the boron content in inorganic calcite grown in artificial seawater

J Uchikawa, DT Harper, DE Penman, JC Zachos… - … et Cosmochimica Acta, 2017 - Elsevier
The ratio of boron to calcium (B/Ca) in marine biogenic carbonates has been proposed as a
proxy for properties of seawater carbonate chemistry. Applying this proxy to planktic …

No ion is an island: Multiple ions influence boron incorporation into CaCO3

MJ Henehan, CDK Gebbinck, JVB Wyman… - … et Cosmochimica Acta, 2022 - Elsevier
Boron isotope ratios–as measured in marine calcium carbonate–are an established tracer of
past seawater and calcifying fluid pH, and thus a powerful tool for probing marine calcifier …

Decoupled carbonate chemistry controls on the incorporation of boron into Orbulina universa

EL Howes, K Kaczmarek, M Raitzsch, A Mewes… - …, 2017 - bg.copernicus.org
In order to fully constrain paleo-carbonate systems, proxies for two out of seven parameters,
plus temperature and salinity, are required. The boron isotopic composition (δ 11 B) of …

Calcification and growth processes in planktonic foraminifera complicate the use of B/Ca and U/Ca as carbonate chemistry proxies

KH Salmon, P Anand, PF Sexton, M Conte - Earth and Planetary Science …, 2016 - Elsevier
Although boron and uranium to calcium ratios (B/Ca, U/Ca) in planktonic foraminifera have
recently received much attention as potential proxies for ocean carbonate chemistry, the …

Boric acid and borate incorporation in inorganic calcite inferred from B/Ca, boron isotopes and surface kinetic modeling

JR Farmer, O Branson, J Uchikawa, DE Penman… - … et Cosmochimica Acta, 2019 - Elsevier
The boron concentration (B/Ca ratio) and isotopic composition (δ 11 B) of biogenic calcite
are widely applied to reconstruct past changes in seawater carbonate chemistry. Knowledge …

The coordination and distribution of B in foraminiferal calcite

O Branson, K Kaczmarek, SAT Redfern, S Misra… - Earth and Planetary …, 2015 - Elsevier
The isotopic ratio and concentration of B in foraminiferal calcite appear to reflect the pH and
bicarbonate concentration of seawater. The use of B as a chemical proxy tracer has the …

Environmental controls on B/Ca in calcite tests of the tropical planktic foraminifer species Globigerinoides ruber and Globigerinoides sacculifer

KA Allen, B Hönisch, SM Eggins, Y Rosenthal - Earth and Planetary …, 2012 - Elsevier
The ratio of boron to calcium (B/Ca) in the calcite tests of planktic foraminifers may serve as
a proxy for past seawater chemistry, but controls on B incorporation are not yet certain. Here …

Evaluating the utility of B/Ca ratios in planktic foraminifera as a proxy for the carbonate system: A case study of Globigerinoides ruber

MJ Henehan, GL Foster, JWB Rae… - Geochemistry …, 2015 - Wiley Online Library
B/Ca ratios in foraminifera have attracted considerable scientific attention as a proxy for past
ocean carbonate system. However, the carbonate system controls on B/Ca ratios are not …

Core-top calibration of B/Ca in Pacific Ocean Neogloboquadrina incompta and Globigerina bulloides as a surface water carbonate system proxy

NBQ Krupinski, AD Russell, DK Pak… - Earth and Planetary …, 2017 - Elsevier
Practical methods for reconstructing past ocean carbonate chemistry are needed to study
past periods of ocean acidification and improve understanding of the marine carbonate …