Intramolecular spodium bonds in Zn (II) complexes: insights from theory and experiment
M Karmakar, A Frontera, S Chattopadhyay… - International Journal of …, 2020 - mdpi.com
Two new dinuclear zinc (II) complexes,[Zn2 (µ 1, 3-OAc)(L1) 2] I· MeOH (1) and [Zn2 (µ 1, 3-
OAc)(L2)(NCS)](2),(where HL1= 2-(((3-(dimethylamino) propyl) amino) methyl)-6-methoxy …
OAc)(L2)(NCS)](2),(where HL1= 2-(((3-(dimethylamino) propyl) amino) methyl)-6-methoxy …
The importance of spodium bonds, H-bonds and π-stacking interactions in the solid state structures of four zinc complexes with tetradentate secondary diamine …
P Middya, M Karmakar, RM Gomila… - New Journal of …, 2023 - pubs.rsc.org
In this manuscript we report the preparation of four new zinc complexes,[{(μ-CH3COO)
ZnL1} 2Zn]· 2DMSO (1),[{(DMF) ZnL1 (μ-CH3COO) ZnL1Zn (N3)}]· 0.64 DMSO· 0.36 EtOH …
ZnL1} 2Zn]· 2DMSO (1),[{(DMF) ZnL1 (μ-CH3COO) ZnL1Zn (N3)}]· 0.64 DMSO· 0.36 EtOH …
Differentiating intramolecular spodium bonds from coordination bonds in two polynuclear zinc (II) Schiff base complexes
Two new zinc (II) complexes,[{N (CN) 2} Zn (L1) Zn {μ-1, 5-N (CN) 2}] 2 (1) and [{μ-1, 5-N
(CN) 2}{N (CN) 2} Zn (L2) Zn {μ-1, 5-N (CN) 2}] n (2){H2L1= 2, 2′-[(2, 2-dimethyl-1, 3 …
(CN) 2}{N (CN) 2} Zn (L2) Zn {μ-1, 5-N (CN) 2}] n (2){H2L1= 2, 2′-[(2, 2-dimethyl-1, 3 …
Spodium bonding in five coordinated Zn (II): A new player in crystal engineering?
This manuscript evidences the existence and importance of spodium bonds (SpB) in solid
state structures involving five-coordinated square-pyramidal Zn (II) spodium atoms. Four …
state structures involving five-coordinated square-pyramidal Zn (II) spodium atoms. Four …
A bowl-shaped phenoxido-bridged binuclear zinc complex: Experimental and theoretical studies
M Azam, G Velmurugan… - Inorganica Chimica …, 2022 - Elsevier
A new dinuclear zinc coordination complex with di (μ-alkoxido) bridge obtained from [[H 2 L=
N, N-(salicyaldene)-1, 3-diaminopropan-2-ol] was investigated by IR, 1 H-& 13 C NMR …
N, N-(salicyaldene)-1, 3-diaminopropan-2-ol] was investigated by IR, 1 H-& 13 C NMR …
Experimental and Theoretical Survey of Intramolecular Spodium Bonds/σ/π-Holes and Noncovalent Interactions in Trinuclear Zn(II)-Salen Type Complex with OCN– …
In this work, one new centrosymmetric trinuclear Zn (II) complex 1,[{(OCN) Zn (L)} 2Zn], using
a salen-type ligand (H2L) in the presence of OCN–was synthesized and characterized via …
a salen-type ligand (H2L) in the presence of OCN–was synthesized and characterized via …
Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between 13C NMR …
BH Ye, XY Li, ID Williams, XM Chen - Inorganic chemistry, 2002 - ACS Publications
Two di-and a tetranuclear zinc− carboxylate complexes with different coordination
modes,[Zn2L (μ1, 3-OAc) 2](ClO4)(1),[Zn2L (μ1, 3-Pro) 2](ClO4)(2), and [Zn2L (μ1, 1 …
modes,[Zn2L (μ1, 3-OAc) 2](ClO4)(1),[Zn2L (μ1, 3-Pro) 2](ClO4)(2), and [Zn2L (μ1, 1 …
Structural investigations, Hirsfeld surface analyses, and molecular docking studies of a phenoxo-bridged binuclear Zinc (II) complex
M Azam, PK Sahoo, RK Mohapatra, M Kumar… - Journal of Molecular …, 2022 - Elsevier
A novel phenoxo-bridged zinc complex,[Zn 2 (L) µ (OO) 2 H 2 OCl 2][L= deprotonated salen
ligand, 2, 2′-((1E, 1′ E)-((2, 2-dimethylpropane-1, 3-diyl) bis (azaneylylidene)) bis …
ligand, 2, 2′-((1E, 1′ E)-((2, 2-dimethylpropane-1, 3-diyl) bis (azaneylylidene)) bis …
Synthesis, crystal structure, spectroscopic properties and DFT calculations of a new Schiff base-type Zinc (II) complex
LQ Chai, JY Zhang, LC Chen, YX Li… - Research on Chemical …, 2016 - Springer
A new mononuclear Zn (II) complex,[Zn (L 2) 2]· CH 3 OH (HL 2= 1-(2-{[(E)-3, 5-dichloro-2-
hydroxybenzylidene] amino} phenyl) ethanone oxime), has been synthesized via …
hydroxybenzylidene] amino} phenyl) ethanone oxime), has been synthesized via …
Spodium bonding and other non-covalent interactions assisted supramolecular aggregation in a new mercury (II) complex of a nicotinohydrazide derivative
G Mahmoudi, E Zangrando, B Miroslaw… - Inorganica Chimica …, 2021 - Elsevier
In this work we report a new Hg (II) coordination compound [Hg (HL)(SCN) 2], which was
readily obtained from a mixture of Hg (SCN) 2 and N'-(1-(pyridin-2-yl) ethylidene) …
readily obtained from a mixture of Hg (SCN) 2 and N'-(1-(pyridin-2-yl) ethylidene) …