[PDF][PDF] A one-pot catalysis combining laccase with Cu (salen) for selective removal of refractory lignin units during oxygen delignification of bamboo kraft pulp.

XF Zhou - 2020 - ipef.br
The catalysis is an alternative to extend the delignification of pulp with molecular oxygen.
This work thus focused on the delignification selectivity and selective removal of refractory …

Copper‐and vanadium‐catalyzed oxidative cleavage of lignin using dioxygen

J Mottweiler, M Puche, C Räuber, T Schmidt… - …, 2015 - Wiley Online Library
Transition‐metal‐containing hydrotalcites (HTc) and V (acac) 3/Cu (NO3) 2⋅ 3 H2O (acac=
acetylacetonate) mixtures were tested for their catalytic activity in the cleavage of the lignin …

Investigation of the chemical basis for inefficient lignin removal in softwood kraft pulp during oxygen delignification

S Fu, LA Lucia - Industrial & engineering chemistry research, 2003 - ACS Publications
In this study, an industrial softwood kraft pulp sample was subjected to an oxygen− alkali
treatment over three consecutive times as part of a broader research effort to identify …

Laccase/mediated oxidation of a lignin model for improved delignification procedures

AM Barreca, M Fabbrini, C Galli, P Gentili… - Journal of Molecular …, 2003 - Elsevier
Laccase oxidises the phenolic but not the non-phenolic subunits of lignin. Redox mediators
drive laccase towards the oxidation of non-phenolic subunits, particularly the benzyl alcohol …

[PDF][PDF] Transition metal-catalysed oxidation of lignin model compounds for oxygen delignification of pulp

V Sippola - 2006 - aaltodoc.aalto.fi
Molecular oxygen (O2) is widely used as a delignification agent in pulp bleaching.
Unfortunately, carbohydrates are attached to a greater extent during oxygen delignification …

Comparison of laccase-catalyzed cross-linking of organosolv lignin and lignosulfonates

T Gillgren, M Hedenström, LJ Jönsson - International journal of biological …, 2017 - Elsevier
Lignin, an underutilized by-product from chemical pulping of wood, can be modified
enzymatically through oxidation by laccase. However, little is known about the molecular …

Mild selective oxidative cleavage of lignin C–C bonds over a copper catalyst in water

Y Hu, L Yan, X Zhao, C Wang, S Li, X Zhang, L Ma… - Green …, 2021 - pubs.rsc.org
The conversion of lignin into aromatics as commodity chemicals and high-quality fuels is a
highly desirable goal for biorefineries. However, the presence of robust inter-unit carbon …

Unraveling the fate of lignin from eucalyptus and poplar during integrated delignification and bleaching

H Wang, B Wang, D Sun, Q Shi, L Zheng… - …, 2019 - Wiley Online Library
Efficient deconstruction of lignocellulose is vitally important for the biorefinery industry
because lignin structures play a crucial role in the high value‐added conversion of lignin. In …

Recent progress on oxygen delignification of softwood kraft pulp

ARP van Heiningen, Y Ji, V Jafari - Cellulose science and …, 2018 - Wiley Online Library
Oxygen delignification is the standard bridging technology placed between pulping and
bleaching. In order to improve the delignification/cellulose degradation selectivity, it is …

Study of typical chemical cleavage during catalytic oxidation of lignin

C Haonan, HU Xiaohong, MA Longlong - CIESC Journal - hgxb.cip.com.cn
Lignin is the most abundant renewable aromatic resource in nature and the basic aromatic
units are linked by C—O and C—C bonds. Oxidative depolymerization can significantly …