Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

[HTML][HTML] Synthesis, catalysis, surface chemistry and structure of bimetallic nanocatalysts

FF Tao - Chemical Society Reviews, 2012 - pubs.rsc.org
Studies of bimetallic catalysts can be tracked back to the early 1960s in the Exxon Research
and Engineering Company. The term''bimetallic clusters''was introduced by John H. Sinfelt in …

Bimetallic nano-particles: featuring structure and reactivity

L Guczi - Catalysis Today, 2005 - Elsevier
Highly dispersed, oxide-or zeolite-supported bimetallic catalysts are widely used in the
catalytic industry, such as in catalytic reforming, nitrogen industry and gas-to-liquid …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Catalysis Synergism by Atomically Precise Bimetallic Nanoclusters Doped with Heteroatoms

X Liu, X Cai, Y Zhu - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Bimetallic catalysts hold promise in tailoring the catalytic activity and selectivity
of transition metals for important chemical processes due to the synergistic coupling …

Bimetallic nanoparticles associating noble metals and first-row transition metals in catalysis

I Mustieles Marin, JM Asensio, B Chaudret - ACS nano, 2021 - ACS Publications
Bimetallic nanoparticles (NPs) are complex systems with properties that far exceed those of
the individual constituents. In particular, association of a noble metal and a first-row …

[HTML][HTML] Action of bimetallic nanocatalysts under reaction conditions and during catalysis: evolution of chemistry from high vacuum conditions to reaction conditions

FF Tao, S Zhang, L Nguyen, X Zhang - Chemical Society Reviews, 2012 - pubs.rsc.org
Bimetallic catalysts are one of the main categories of metal catalysts due to the tunability of
electronic and geometric structures through alloying a second metal. The integration of a …

[HTML][HTML] Designing bimetallic catalysts for a green and sustainable future

M Sankar, N Dimitratos, PJ Miedziak… - Chemical Society …, 2012 - pubs.rsc.org
This Critical Review provides an overview of the recent developments in the synthesis and
characterization of bimetallic nanoparticles. Initially the review follows a materials science …

A general approach to mono-and bimetallic organometallic nanoparticles

S Mavila, I Rozenberg, NG Lemcoff - Chemical Science, 2014 - pubs.rsc.org
A comprehensive methodology to prepare nanometric size organometallic particles (ONPs)
containing rhodium (I), iridium (I) and nickel (0) with ROMP-derived polycycloocta-1, 5-diene …

Metallic nanoparticles in heterogeneous catalysis

A Sápi, T Rajkumar, J Kiss, Á Kukovecz, Z Kónya… - Catalysis letters, 2021 - Springer
Heterogeneous catalysis is a chemical process achieved at solid–gas or solid–liquid
interfaces. Many factors including the particle size, shape and metal-support interfaces can …